α-Oxidation of ketones using n-cation radicals

DOI: 10.1016/S0040-4020(01)82017-2

Source and publish data:

Tetrahedron p. 2371 - 2380 (1990)

Update date:2022-08-10

Topics:

Authors:

Schulz, Manfred

Kluge, Ralph

Sivilai, Li

Kamm, Birgit

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Article abstract of DOI:10.1016/S0040-4020(01)82017-2

Six-membered ring ketones and acyclic ketones were oxidized by stable triarylamminium radical cations in moist acetonitrile at room temperature in the presence of a base to α-hydroxy ketones in good yield. Five-membered ring ketones gave the corresponding αβ-unsaturated compounds.

Full text of DOI:10.1016/S0040-4020(01)82017-2

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