Tetrahedron Letters p. 3457 - 3460 (1993)
Update date:2022-08-17
Topics:
Takuwa, Akio
Shiigi, Junji
Nishigaichi, Yutaka
(E)- and (Z)-Allylic tributyltins add to aromatic aldehydes to afford regioreversed α-adduct predominantly with almost complete retention of the stereochemistry of the allylic groups under photochemical conditions.The photoinduced single electron transfer mechanism is proposed.
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