Journal of the Chemical Society. Chemical communications p. 1836 - 1837 (1987)
Update date:2022-08-11
Topics:
Buss, Antony D.
Hirst, Gavin C.
Parsons, Philip J.
Alkyl α-phenylsulphonylacrylates have been made as geometrically pure isomers; the Z-isomer reacts with dienes in Diels-Alder cycloadditions to afford the oposite regiochemistry to that observed with the E-isomer and this provides a useful method for reversing normal carbonyl directing effects.
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