International Journal of Chemical Kinetics p. 983 - 993 (1993)
Update date:2022-08-11
Topics:
Hidaka
Nakamura
Kawano
CF3Br-H2 mixtures highly diluted with Ar were studied by using a time-resolved IR-emission of HBr and a gas-chromatography for reaction products. The temperature range covered was 1000-1600 K and the total pressure behind the reflected shock waves used was 1. 2-2.6 atm. CF3H, C2F6, and C2F4 were produced and the yields of these products were determined as a function of temperature. The main product under our experimental conditions was CF3H. The mechanism and the rate constants of CF3Br--H2 reaction at high temperatures were discussed. The experimental data was satisfactorily modeled using a 14-reaction mechanism. Reaction (5) played an important role in the formation of CF3H together with reaction (4).
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