A Chemical Model for the Activation of Pyruvate-Formate-Lyase

DOI: 10.1016/0040-4039(95)00167-B

Source and publish data:

Tetrahedron Letters p. 2105 - 2108 (1995)

Update date:2022-08-16

Topics:

Authors:

Baldwin, Jack E.

Brown, David

Scudder, Paul H.

Wood, Mark E.

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Article abstract of DOI:10.1016/0040-4039(95)00167-B

A chemical model is described for the activation of the carbon-centred radical-based enzyme, pyruvate-formate-lyase.The feasibility of a 5'-deoxyadensyl radical abstracting a hydrigen atom from C-2 of a peptideglycine residue has been demonstrated in an intramolecular process.

Full text of DOI:10.1016/0040-4039(95)00167-B

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