Tetrahedron Letters p. 2105 - 2108 (1995)
Update date:2022-08-16
Topics:
Baldwin, Jack E.
Brown, David
Scudder, Paul H.
Wood, Mark E.
A chemical model is described for the activation of the carbon-centred radical-based enzyme, pyruvate-formate-lyase.The feasibility of a 5'-deoxyadensyl radical abstracting a hydrigen atom from C-2 of a peptideglycine residue has been demonstrated in an intramolecular process.
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