Optisch aktive Uebergangsmetall-Komplexe XCV. Optisch reines 3a,4,5,6,7,7a-Hexahydro-2-phenyl-4,7-methano-1H-inden-1-on durch asymmetrische Khand-Reaktion

Article abstract of DOI:10.1016/0022-328X(88)89044-2

The prochiral complex Co2(CO)6(HC2Ph) (I) obtained from the reaction of Co2(CO)8 with phenylacetylene, after reaction with the optically active phosphane Glyphos (II) gives the complex Co2(CO)5(HC2Ph)(Glyphos) which consists of two diastereomers (IIIa and