SYNTHESIS OF (+/-) SILPHINENE

DOI: 10.1016/0040-4039(88)80029-7

Source and publish data:

Tetrahedron Letters p. 107 - 108 (1988)

Update date:2022-08-11

Topics:

Authors:

Rao, Y. Koteswar

Nagarajan, M.

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Article abstract of DOI:10.1016/0040-4039(88)80029-7

Synthesis of (+/-) silphinene from readily available 2,4,4-trimethylcyclopentanone is reported.The stereospecific radical cyclization of 8 giving 9 exclusively is the cornerstone of the synthesis.

Full text of DOI:10.1016/0040-4039(88)80029-7

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Product name:Thiocarbonic acid O-[1-methyl-3-((1R,3aS)-2,2,3a-trimethyl-5-oxo-1,2,3,3a,4,5-hexahydro-pentalen-1-yl)-propyl] ester O-p-tolyl ester

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