Russian Chemical Bulletin p. 1961 - 1962 (1997)
Update date:2022-08-24
Topics:
Luzikova
Bumagin
Palladium- and iodide ion-catalyzed acyldemercuration of R2Hg(RHgI) by aroyl chlorides (ArCOCl) can be carried out in aqueous media. Nonsymmetrical ketones (ArCOR) are obtained in high yields along with oxidative demercuration products (R2) in trace quantities. The possible reaction mechanism and the role of the iodide ion are discussed.
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Doi:10.1016/S0039-128X(69)80059-0
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