Tetrahedron Letters p. 115 - 116 (1998)
Update date:2022-08-29
Topics:
Field, Leslie D.
Sternhell, Sever
Wilton, Howard V.
Treatment of naphthalene and biphenyl with alumina and hydrogen in a vibratory mill for about 5h at ambient temperature gives up to 75% and 15% of tetralin and phenylcyclohexane respectively. This suggests that the previously reported disproportionation of naphthalene and biphenyl to give tetralin and phenylcyclohexane by analogous treatment under nitrogen proceeds at least partially by a step involving molecular hydrogen. However, these observations are not general because identical mechanical treatment of trans- stilbene under hydrogen gave less bibenzyl than under nitrogen.
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