THE GENERATION AND E.S.R. OBSERVATION OF A DERIVATIVE OF VINYL-TMM (2-METHYLENECYCLOHEPT-3-EN-1,5-DYIL)

DOI: 10.1016/S0040-4039(00)84447-0

Source and publish data:

Tetrahedron Letters p. 2053 - 2056 (1986)

Update date:2022-08-16

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Authors:

Bushby, Richard J.

Jarecki, Christine

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Article abstract of DOI:10.1016/S0040-4039(00)84447-0

Photolysis of 6,7-diaza-2-methylenebicyclo<3.2.2>nona-3,6-diene in a glassy matrix at 77K gives the triplet biradical, 2-methylenecyclohept-3-en-1,5-diyl, which shows <*>D/hc<*>0.019 and <*>E/hc<*>0.006 cm^-1.

Full text of DOI:10.1016/S0040-4039(00)84447-0

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