Photolysis of 2,3:5,6-Dibenzo-7,7,8,8-tetraisopropyl-7,8-disilabicycloocta-2,5-diene: Evidence for Cyclodimerization of a Disilene

DOI: 10.1039/c39840000724

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 724 - 725 (1984)

Update date:2022-08-29

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Authors:

Matsumoto, Hideyuki

Arai, Takeshi

Watanabe, Hamao

Nagai, Yoichiro

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Article abstract of DOI:10.1039/c39840000724

Evidence for disilene dimerization was obtained by generating tetraisopropyldisilene from the title compound via the photochemical retrodiene process which produced the expected dimerization product, octaisopropylcyclotetrasilane (30percent), in addition to the H-abstraction product, 1,1,2,2-tetraisopropyldisilane (5percent).

Full text of DOI:10.1039/c39840000724

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