Journal of the American Chemical Society p. 1109 - 1113 (1984)
Update date:2022-08-11
Topics:
Menger
Doll
Kinetic studies of micellar olefin oxidation by permanganate ion show that a terminal olefin is oxidized 2 orders of magnitude faster than internal olefins. This is interpreted in terms of coiling and disorder which place chain termini in the water-rich Stern region. The results are not consistent with the Dill-Flory and Fromherz models.
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