Chemistry Letters p. 1535 - 1536 (1984)
Update date:2022-08-10
Topics:
Ohshima, Masahiro
Murakami, Masahiro
Mukaiyama, Teruaki
A mixed ortho ester is prepared under mild conditions from an allyl alcohol and a ketene acetal in the presence of PdCl2(COD).The ortho ester thus formed is successively treated with a catalytic amount of PdCl2(PPh3)2 in refluxing p-xylene to afford a γ,δ-unsaturated ester in a high yield under neutral conditions.
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Doi:10.1515/zpch-2014-0538
(2014)Doi:10.1063/1.448915
(1985)Doi:10.1039/c7cp07747e
(2018)Doi:10.1021/jacs.7b10433
(2018)Doi:10.1002/hlca.19840670620
(1984)Doi:10.1071/CH9650583
(1965)