Doppler-limited dye laser excitation spectroscopy of the >A (000)->A'(000) band of HSiF

Article abstract of DOI:10.1063/1.448915

The <*>A (000)-<*>A'(000) band of HSiF was observed by Doppler-limited dye laser excitation spectroscopy.The HSiF molecule was produced by the reaction of SiH3F with microwave discharge products of CF4.The observed spectrum was found to be almost free of perturbations and was readily assigned to about 1300 transitions of K_a' - K_a = 5-6, 4-5, 3-4, 2-3, 1-2, 0-1,1-0, 2-1, 3-2, 4-3, 5-4, 0-0,1-1, and 2-0.A least-squares analysis of the observed spectrum yielded the rotational constants and the centrifugal distortion constants for both the <*> and <*> states.The molecular structure was discussed using the observed rotational constants.

Full text of DOI:10.1063/1.448915

Dopplerlimited dye laser excitation spectroscopy of the Ã1 A’’(000)–X̃1 A’(000) band
of HSiF
Tetsuo Suzuki, Kohzo Hakuta, Shuji Saito, and Eizi Hirota
Citation: The Journal of Chemical Physics 82, 3580 (1985); doi: 10.1063/1.448915
View online: http://dx.doi.org/10.1063/1.448915
View Table of Contents: http://scitation.aip.org/content/aip/journal/jcp/82/8?ver=pdfcov
Published by the AIP Publishing
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
155.33.120.209 On: Wed, 03 Dec 2014 05:49:16

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
155.33.120.209 On: Wed, 03 Dec 2014 05:49:16

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
155.33.120.209 On: Wed, 03 Dec 2014 05:49:16

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
155.33.120.209 On: Wed, 03 Dec 2014 05:49:16