Journal of the Chemical Society. Chemical communications p. 447 - 449 (1983)
Update date:2022-08-25
Topics:
Takeuchi, Hiroshi
Takano, Katsuyuki
Aromatic N-substitution by phenylnitrenium ions generated from phenyl azide in the presence of a catalytic amount of trifluoromethanesulphonic acid gave diarylamines (in especially good yield in the reaction with biphenyl or naphthalene), whereas naphthylnitrenium ions from 1-azidonaphthalene react with benzene to afford a C-substitution product, 1-amino-4-phenylnaphthalene.
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(1983)
