Tetrahedron p. 4259 - 4266 (1986)
Update date:2022-08-28
Topics:
Ayres, David C.
Levy, Daniel P.
Whereas free phenols are rapidly oxidised by ruthenium tetroxide with fragmentation, the aromatic nuclei of their O-trifluoroacetates are unaffected by the reagent in dry conditions.This led to a method for the controlled oxidation of functionalised phenols which is demonstrated here by the selective cleavage of hydroxyarylalkenes, coumarins and aromatic steroidal alkenes.
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