Ortho Enhancement in the Ozone-Mediated Nitration of Some Aromatic Carbonyl Compounds with Nitrogen Dioxide

DOI: 10.1246/cl.1993.1421

Source and publish data:

Chemistry Letters p. 1421 - 1424 (1993)

Update date:2022-08-10

Topics:

Authors:

Suzuki, Hitomi

Murashima, Takashi

Tatsumi, Atsuo

Kozai, Iku

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1993.1421

Alkyl aryl ketones react smoothly with nitrogen dioxide at low temperatures in the presence of ozone to give a mixture of ortho and meta nitration products (o/m = 1.1-3.8/1.0), the former becoming predominant with the increasing size of alkyl moiety.

Full text of DOI:10.1246/cl.1993.1421

Products guided by the article

Product name:3-Nitroacetophenone

Cas No:121-89-1

R&D Labs maybe for 121-89-1

SHENZHEN PENGCHENG REDSTAR INDUSTRY CO.,LTD

Contact:+86-755-82412922

Address:Room 8066, East Block, Square City, Jiabin Road, Luohu District
Hubei Lansun Biochemical Pharmaceutical Co., Ltd

Contact:714-6395977

Address:No. 81 Pengcheng Avenue, economic and technological development zone, Huangshi City, Hubei Province,China
Chameleon Specialty Chemicals

Contact:+44 7958 511245

Address:PO Box 469, Manchester, UK
Shifang Taifeng New Flame Retardant Co., Ltd

Contact:02884721008

Address:tingjiang industrial park, hefeng town
JIAXING SUNS INTERNATIONAL TRADE CO LTD

Contact:18367306858

Address:No.123,Huixin Avenue,Huimin Dist

Relevant to this article

Doi:10.1007/BF02978882
(1935)
Doi:10.1021/ja00440a088
(1976)
Rh₂(OAc)₄/CeCl₃-catalyzed olefination of carbonylferrocenes with α-diazocarbonyl compounds: A convenient synthesis of alkenylferrocenes

Doi:10.1055/s-0031-1290612
(2012)
Novel α-amino-3-hydroxy-5-methylisoxazole-4-propionate receptor antagonists: Synthesis and structure-activity relationships of 6-(1H- imidazol-1-yl)-7-nitro-2,3(1H,4H)-pyrido[2,3-b]pyrazinedione and related compounds

Doi:10.1021/jm950304+
(1996)
Unexpected synthesis of novel 2-pyrone derivatives: crystal structures, Hirshfeld surface analysis and computational studies

Doi:10.1080/07391102.2020.1780943
(2021)
Inhibition of glucose- and calcium-induced insulin secretion from βTC3 cells by novel inhibitors of protein isoprenylation

Doi:10.1124/jpet.102.036160
(2002)

Article Doi