Ortho Enhancement in the Ozone-Mediated Nitration of Some Aromatic Carbonyl Compounds with Nitrogen Dioxide

DOI: 10.1246/cl.1993.1421

Source and publish data:

Chemistry Letters p. 1421 - 1424 (1993)

Update date:2022-08-10

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Authors:

Suzuki, Hitomi

Murashima, Takashi

Tatsumi, Atsuo

Kozai, Iku

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Article abstract of DOI:10.1246/cl.1993.1421

Alkyl aryl ketones react smoothly with nitrogen dioxide at low temperatures in the presence of ozone to give a mixture of ortho and meta nitration products (o/m = 1.1-3.8/1.0), the former becoming predominant with the increasing size of alkyl moiety.

Full text of DOI:10.1246/cl.1993.1421

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