Journal of the American Chemical Society p. 6360 - 6368 (1982)
Update date:2022-08-10
Topics:
Marsella, John A.
Huffman, John C.
Caulton, Kenneth G.
Longato, Bruno
Norton, Jack R.
Reaction of Cp2ZrMe2 with CpMo(CO)3H yields methane and Cp2ZrMeMo(CO)3Cp (1), which has two terminal carbonyl ligands and a third carbonyl with a low (1545 cm-1) stretching frequency.Added gaseous CO inserts into the Zr-Me bond in 1 to form the
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