Dinuclear Elimination as a Route to Unusual Bridging Carbonyls and Acetyls in Heterobimetallic Complexes

DOI: 10.1021/ja00387a034

Source and publish data:

Journal of the American Chemical Society p. 6360 - 6368 (1982)

Update date:2022-08-10

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Authors:

Marsella, John A.

Huffman, John C.

Caulton, Kenneth G.

Longato, Bruno

Norton, Jack R.

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Article abstract of DOI:10.1021/ja00387a034

Reaction of Cp2ZrMe2 with CpMo(CO)3H yields methane and Cp2ZrMeMo(CO)3Cp (1), which has two terminal carbonyl ligands and a third carbonyl with a low (1545 cm^-1) stretching frequency.Added gaseous CO inserts into the Zr-Me bond in 1 to form the

Full text of DOI:10.1021/ja00387a034

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