Journal of the Chemical Society. Chemical communications p. 879 - 881 (1984)
Update date:2022-08-28
Topics:
Fontecave, Marc
Mansuy, Daniel
FeCl3 and Fe(acac)3 (acac = acetylacetonato), like Fe(TPP)(Cl) (TPP = tetraphenylporphyrinato), catalyse the epoxidation of styrene and stilbenes and the oxidation of non-1-ene by PhIO; however, several characteristics of the oxidations catalysed by non-porphyrin iron complexes, such as stereospecificity and sensitivity to dioxygen, are very different from those of the corresponding reactions catalysed by Fe(TPP)(Cl).
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