RhCl(PPh3)3/NaI catalyst system for hydrosilylation of 1-alkynes: Stereodivergent syntheses of E-and Z-alkenylsilanes with heteroatom substituents on silicon

DOI: 10.1246/cl.1998.443

Source and publish data:

Chemistry Letters p. 443 - 444 (1998)

Update date:2022-08-10

Topics:

Authors:

Mori, Atsunori

Takahisa, Eisuke

Kajiro, Hiroshi

Hirabayashi, Kazunori

Nishihara, Yasushi

Hiyama, Tamejiro

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Article abstract of DOI:10.1246/cl.1998.443

Both (E)-and (Z)-alkenylsilanes are synthesized by the reaction of hydrosilanes and 1-alkynes catalyzed by RhCl(PPh₃)₃/NaI or RhI(PPh₃)₃ highly selectively.

Full text of DOI:10.1246/cl.1998.443

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