REACTIONS OF THE AROMATIC ORGANOCOPPER COMPOUNDS WITH CHOSEN BORON COMPOUNDS

DOI: 10.1016/0022-328X(85)87438-6

Source and publish data:

Journal of Organometallic Chemistry p. 257 - 266 (1985)

Update date:2022-08-16

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Authors:

Kalbarczyk, Elzbieta

Pasynkiewicz, Stanislaw

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Article abstract of DOI:10.1016/0022-328X(85)87438-6

The reaction of arylorganocopper compounds Cu4Ar4 (Ar = Ph, C6H4CH2NMe2-2) with BR3 boron compounds (BF3, BEt3, BPh-9-BBN, BAr-9-BBN, Ar = C6H4CH2NMe2-2-9-BBN = 9-borabicyclo<3.3.1>bicyclononyl) was investigated.A mechanism involving polymer formation in the first step of the reaction with subsequent intramolecular rearrangement under abstraction of BR'R2 is proposed.

Full text of DOI:10.1016/0022-328X(85)87438-6

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