Tetrahedron Letters p. 7657 - 7659 (1999)
Update date:2022-08-11
Topics:
Tymonko, Steven A.
Nattier, Bryce A.
Mohan, Ram S.
Benzoins are oxidized to benzils in excellent yields by 0.4 equivalents of Bi(NO3)3·5H2O and 4 mol% of Cu(OAc)2. Bi(NO3)3·5H2O is a stable, inexpensive, commercially available solid. The relatively low cost and low toxicity of bismuth(III) nitrate makes this procedure a particularly attractive method for oxidation of benzoins.
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