Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 629 - 634 (1984)
Update date:2022-08-11
Topics:
Takahashi, Nobuo
Matsuo, Hiroyuki
Kobayashi, Masayoshi
Ethylene hydroformylation over Rh-Y zeolite has been studied kinetically.The rate of formation of propionaldehyde is approxymately proportional to the partial pressure of ethylene and decreases as the partial pressure of carbon monoxide increases.The rate is proportional to the square root of the partial pressure of hydrogen.In the case of ethylene hydroformylation with deuterium almost no appreciable isotope effect on the rate was observed.On the basis of these results a reaction mechanism is proposed via the formation of a propionyl intermediate by the reaction between an ethyl intermediate and adsorbed carbon monoxide.The propionyl-intermediate-formation step is proposed to be rate determining for ethylene hydroformylation over the Rh-Y zeolite.
View MoreJinan Jiaquan Chemical Co.,Ltd
Contact:+86-531-62318366
Address:Room 502 of Yidonghuayuan No.601 Huaxin Road Licheng District Jinan China
Shanghai Sungo Technology Chemical Co., Ltd
Contact:0086-21-51385579
Address:Room2010, F/20, Tonghua Plaza, NO 345 Jinxiang Road, Jinqiao Export Processing Zone, Shanghai, 201206 P.R.CHINA
JinTan Pingsheng Chemical Co.,Ltd
Contact:+86-519-82828200
Address:NO.11Danfengxilu Road,Jintan City,Jiangsu,China
Wuhan Silworld Chemical Co.,Ltd
website:http://www.silworldchemical.com
Contact:+86-27-85613400
Address:No.198 jiangjun Road, Wuhan,China 430033
Kaiping Genuine Biochemical Pharmaceutical Co.,Ltd.
Contact:+86-750-2881198
Address:No.1, Xinke Road, Shatang Town, Kaiping, Guangdong Province, P.R.China
Doi:10.1039/P29920001541
(1992)Doi:10.1021/j100198a030
(1992)Doi:10.1246/bcsj.31.387
(1958)Doi:10.1016/j.jallcom.2015.01.065
(2015)Doi:10.1016/j.tetlet.2014.12.061
(2015)Doi:10.1002/anie.201001517
(2010)
