Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 629 - 634 (1984)
Update date:2022-08-11
Topics:
Takahashi, Nobuo
Matsuo, Hiroyuki
Kobayashi, Masayoshi
Ethylene hydroformylation over Rh-Y zeolite has been studied kinetically.The rate of formation of propionaldehyde is approxymately proportional to the partial pressure of ethylene and decreases as the partial pressure of carbon monoxide increases.The rate is proportional to the square root of the partial pressure of hydrogen.In the case of ethylene hydroformylation with deuterium almost no appreciable isotope effect on the rate was observed.On the basis of these results a reaction mechanism is proposed via the formation of a propionyl intermediate by the reaction between an ethyl intermediate and adsorbed carbon monoxide.The propionyl-intermediate-formation step is proposed to be rate determining for ethylene hydroformylation over the Rh-Y zeolite.
View MoreNEW FORTUNE INDUSTRIAL CO.,LTD.
website:http://newfortune.lookchem.com/
Contact:+86-25-8645-9456
Address:C4-105 GREEN ISLAND FLOWER TOWN
Contact:+86-838-5655598
Address:Guanghan Nanfeng Industrial Zone
Chemieliva Pharmaceutical Co., Ltd.
website:http://www.chemieliva.com
Contact:+86-23-67770219
Address:99 Longhua Road, Yubei District, 401147, Chongqing, China Email: sales@chemieliva.com Tel:0086-23-67770219 Fax: 0086-23-67770220 Attn: Andy Huang
Contact:
Address:
Geen Chemical Technology Co., Ltd
Contact:86-769-21660847
Address:1408, Yingfeng Commercial Center, Nancheng District
Doi:10.1039/P29920001541
(1992)Doi:10.1021/j100198a030
(1992)Doi:10.1246/bcsj.31.387
(1958)Doi:10.1016/j.jallcom.2015.01.065
(2015)Doi:10.1016/j.tetlet.2014.12.061
(2015)Doi:10.1002/anie.201001517
(2010)
