Journal of Organometallic Chemistry p. 31 - 34 (1995)
Update date:2022-08-29
Topics:
Chang, Biau-Hung
Octacarbonyldicobalt has been found to be a very effective catalyst for both converting allylic ethers to their corresponding acetals in the presence of an alcohol and hydrolyzing allylic ethers to aldehydes.High yields (> 95percent) were obtained in a very short reaction time under mild carbon monoxide pressure.Iron pentacarbonyl was also found to be an active catalyst but less effective than Co2(CO)8Keywords: Cobalt; Acetal; Aldehyde; Allyl; Carbonylation; Ether
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