Tetrahedron Letters p. 3509 - 3512 (1981)
Update date:2022-08-11
Topics:
Adam, Waldemar
Rodriguez, Augusto
On heating the furan endoperoxide (2) rearranges into the enol ester (4) and the bicyclic ozonide (3) affords instead the rearranged ozonide (7).The process (2)->(4) represents an intramolecular Baeyer-Villiger rearrangement presumably via the dioxirane (D-2), while the process (3)->(7) represents intramolecular trapping of the carbonyl oxide (C-3).
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