Chemistry Letters p. 393 - 394 (1995)
Update date:2022-08-11
Topics:
Katsumura, Shigeo
Yamamoto, Noriyoshi
Fukuda, Etsuko
Iwama, Seiji
D-Threo- and D-erythro-sphingosine, (1) and (2), inhibitors of protein kinase C, have been efficiently synthesized from glycidol through (R)-4-methoxycarbonyloxazolidinone (3) by selective mono-alkylation followed by highly diastereoselective reduction of the tin-substituted pentadecenyl ketone 5.
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