Tetrahedron Letters p. 3297 - 3300 (1994)
Update date:2022-08-28
Topics:
Semenzin, Delphine
Etemad-Moghadam, Guita
Albouy, Dominique
Koenig, Max
The generation of phosphine PH3 by alkaline hydrolysis of red phosphorus is realized. The subsequent alkylation of PH3 by terminal alkenes and alkynes in basic media leading to the corresponding aliphatic and vinylic phosphine derivatives can occur by two-steps or one-pot reaction by a Michael-like reaction mechanism.
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