Tetrahedron Letters p. 1523 - 1526 (1995)
Update date:2022-08-11
Topics:
Iwahama, Takahiro
Sakaguchi, Satoshi
Nishiyama, Yutaka
Ishii, Yasutaka
α-Hydroxy ketones and vic-diols were successfully oxidized to the corresponding diketones with acqueous hydrogen peroxide in the presence of a catalytic amount of peroxotungstophosphate (PCWP). This method provides a straightforward route of 1,2-diketones which are difficult to prepare by conventional oxidation of vic-diols.
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