Photolysis of Ozonides in the Gas Phase

DOI: 10.1246/bcsj.56.655

Source and publish data:

Bulletin of the Chemical Society of Japan p. 655 - 656 (1983)

Update date:2022-08-25

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Authors:

Hatakeyama, Shiro

Akimoto, Hajime

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Article abstract of DOI:10.1246/bcsj.56.655

Photolysis of four kinds of simple ozonides (ethene, propene, 2-butene, and isobutene ozonides) in the gas phase were carried out.The contribution of the double-β-scission mechanism was 4-13percent.The main reaction path is proposed to be intramolecular hydrogen abstraction followed by radical forming unimolecular decomposition.

Full text of DOI:10.1246/bcsj.56.655

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