Journal of the Chemical Society. Chemical communications p. 951 - 952 (1989)
Update date:2022-08-15
Topics:
Kawahara, Nobuo
Nozawa, Koohei
Nakajima, Shoichi
Kawai, Ken-Ichi
Yamazaki, Mikio
The structure elucidation of emethallicins B (1) and C (2), novel epitetrathiodioxopiperazines, possessing strong inhibitory activity of the histamine release from mast cells, isolated from the mycelial extract of Emericella heterothallica (mating type a), is reported, based on their 1H and 13C n.m.r. spectra and a chemical correlation of emethallicin A (10) with apoaranotin (11); they are diesters of two C 6-C2 acids having the same basic skeletons as apoaranotin (11) and aranotin (13), respectively.
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