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Bis-trimethylsilanyl-acetonitrile (also known as bis-(trimethylsilyl)-acetonitrile) is a silicon-containing nitrile compound formed as a product in the silico-alkylation reaction of acetonitrile with trimethylchlorosilane and sodium. It is one of several derivatives generated in this process, alongside other silated species such as trimethylisocyanosilane and cyanomethyltrimethylsilane. The study highlights its formation under specific reaction conditions, though its properties and reactivity are less emphasized compared to the unusual ketenimine byproduct. bis-trimethylsilanyl-acetonitrile's stability and behavior under different conditions, such as hydrolysis, are not detailed in the abstract, but its presence underscores the diversity of products achievable through silico-alkylation reactions.

18881-60-2

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18881-60-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 18881-60-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,8,8,8 and 1 respectively; the second part has 2 digits, 6 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 18881-60:
(7*1)+(6*8)+(5*8)+(4*8)+(3*1)+(2*6)+(1*0)=142
142 % 10 = 2
So 18881-60-2 is a valid CAS Registry Number.

18881-60-2Relevant academic research and scientific papers

Electrosynthesis of α-(silyl)alkylnitriles

Constantieux,Picard

, p. 3895 - 3907 (1997)

Sacrificial anode technique has been used to synthetize title compounds in two different ways. First, use was made of α-chloronitriles as the starting materials, zinc as the anode and a THF-HMPA mixture as the solvent. Second, use of an aluminium-made anode, the nitrile being at the same time the substrate and the solvent was shown to be also efficient.

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