18881-60-2

Basic information

• Product Name: bis-trimethylsilanyl-acetonitrile
• Synonyms: bis-trimethylsilanyl-acetonitrile
• CAS NO: 18881-60-2
• Molecular Weight: 185.417
• Mol File: 18881-60-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: bis-trimethylsilanyl-acetonitrile(CAS DataBase Reference)
• NIST Chemistry Reference: bis-trimethylsilanyl-acetonitrile(18881-60-2)
• EPA Substance Registry System: bis-trimethylsilanyl-acetonitrile(18881-60-2)

Safety Data

• Hazardous Substances Data: 18881-60-2(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 60-29-7 diethyl ether 
• 75-05-8 acetonitrile 
• 3018-12-0 dichloroacetonitrile 
• 107-14-2 chloroacetonitrile 

Downstream Products

• 28446-72-2 (2E)-3-(4-chlorophenyl)acrylonitrile 
• 37627-41-1 (Z)-3-(4-chlorophenyl)propenenitrile 
• 30115-95-8 (Z)-3-(4-methoxy-phenyl)-acrylonitrile 
• 14482-11-2 (E)-p-methoxycinnamonitrile 
• 110729-76-5 (2E,4E)-4-Methyl-5-phenyl-penta-2,4-dienenitrile 
• 19124-15-3 4-methyl-2-pentenenitrile 
• 6651-34-9 2-methyl-1-(trimethylsilyloxy)-1-propene 
• 13735-81-4 1-styrenyloxytrimethylsilane 
• 14368-40-2 (E)-3-phenyl-2-butenenitrile 
• 5732-88-7 cyclopentylideneacetonitrile 
• 28446-70-0 (E)-4-methylcinnamonitrile 
• 35121-92-7 3-(4-methylphenyl)-prop-2-enyl nitrile 
• 4435-18-1 2-cyclohexylideneacetonitrile 
• 130130-18-6 [1-(4-Methoxy-phenyl)-2-((E)-1-methyl-2-phenyl-vinyl)-4-oxo-3-trimethylsilanyloxy-azetidin-3-yl]-acetonitrile 

Relevant articles and documents

Electrosynthesis of α-(silyl)alkylnitriles

Sacrificial anode technique has been used to synthetize title compounds in two different ways. First, use was made of α-chloronitriles as the starting materials, zinc as the anode and a THF-HMPA mixture as the solvent. Second, use of an aluminium-made anode, the nitrile being at the same time the substrate and the solvent was shown to be also efficient.