ENANTIOMERICALLY PURE α',β'-DIFUNCTIONALIZED α,β-ENONES BY HIGHLY DIASTEREOSELECTIVE NUCLEOPHILIC ALKENOYLATION OF CHIRAL ALDEHYDES

DOI: 10.1016/S0040-4039(00)99158-5

Source and publish data:

Tetrahedron Letters p. 2919 - 2922 (1989)

Update date:2022-08-16

Topics:

Authors:

Tebben, Petra

Reggelin, Michael

Hoppe, Dieter

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Article abstract of DOI:10.1016/S0040-4039(00)99158-5

The nucleophilic alkenoylation of protected chiral α-oxy and α-amino alkanals 3 by lithiated 1-(p-toluenesulfonyl)-2-alkenyl carbamates 2 proceeds with virtually complete stereoselectivity to form the syn-diastereoisomers of the title compounds 4.

Full text of DOI:10.1016/S0040-4039(00)99158-5

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