The first and simple synthesis of indole alkaloid, bipolaramide

DOI: 10.3987/COM-95-S21

Source and publish data:

Heterocycles p. 281 - 287 (1996)

Update date:2022-07-30

Topics:

Authors:

Somei, Masanori

Kawasaki, Toshiya

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Article abstract of DOI:10.3987/COM-95-S21

The first and simple total synthesis of bipolaramide was achieved in 31 % overall yield from (2S)-2,3-dihydroindole-2-carboxylic acid in three (or two) steps. Derivatives of bipolaramide having halogen, alkenyl, nitro, or azido substitueras were also prepared.

Full text of DOI:10.3987/COM-95-S21

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Product name:(6aS-cis)-4-hydroxy-6a,7,13a,14-tetrahydropyrazino<1,2-a:4,5-a'>diindole-6,13-dione

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