Journal of Organometallic Chemistry p. 197 - 202 (1993)
Update date:2022-08-12
Topics:
Watanabe, Masanobu
Iwamoto, Toschitake
Sano, Hirotoshi
Motoyama, Izumi
Oxidation of 1,1''-biruthenocene with iodoruthenocenium(IV)+Y- salts in CH2Cl2 gives iodo-1,1''-biruthenocenium(II,IV)+Y- salts (Y = PF6, BF4, 2,4,6-(NO2)3C6H2O, CCl3COO * CCl3COOH).The electron exchange reaction between RuII and RuIV with iodide, migration was investigated by temperature-dependent 1H-NMR spectroscopy in CD3COCD3 and the mixed-solvent solutions CDCl3-CD3COCD3, CDCl3-CD3CN and CCl4-CD3COCD3 with a range of mixing ratios.The activation energy of the reaction increases as the concentration of low dielectric constant solvent increases.
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