Journal of Organometallic Chemistry p. 197 - 202 (1993)
Update date:2022-08-12
Topics:
Watanabe, Masanobu
Iwamoto, Toschitake
Sano, Hirotoshi
Motoyama, Izumi
Oxidation of 1,1''-biruthenocene with iodoruthenocenium(IV)+Y- salts in CH2Cl2 gives iodo-1,1''-biruthenocenium(II,IV)+Y- salts (Y = PF6, BF4, 2,4,6-(NO2)3C6H2O, CCl3COO * CCl3COOH).The electron exchange reaction between RuII and RuIV with iodide, migration was investigated by temperature-dependent 1H-NMR spectroscopy in CD3COCD3 and the mixed-solvent solutions CDCl3-CD3COCD3, CDCl3-CD3CN and CCl4-CD3COCD3 with a range of mixing ratios.The activation energy of the reaction increases as the concentration of low dielectric constant solvent increases.
Contact:+86-10-59484199
Address:No.58-A1026 Liangguan Street
Contact:+86-15995924277
Address:WuZhongOu suzhou new south road 89
Shanghai Bocimed Pharmaceutical Co., Ltd.
website:http://www.bocimed.com
Contact:+86-21-68861632
Address:Building 1, Lane 647, Songtao Road, Zhangjiang High-Tech Park, Shanghai
Contact:+86-10-67147360/67107388
Address:No.18 Guangming Zhongjie, Chongwen District, Beijing, 100061, China
WENZHOU M&C FOREIGN TRADE CO.,LTD.
Contact:+86-577-88862917
Address:No.8 Liming West Road,Wenzhou,zhejiang,China
Doi:10.1017/S002185379900763X
()Doi:10.1039/c4cc07978g
(2015)Doi:10.1016/S0040-4039(97)10023-5
(1997)Doi:10.1039/c5dt01305d
(2015)Doi:10.1021/om049601f
(2005)Doi:10.1016/j.dyepig.2019.107635
(2019)
