A new route to early-late heterobimetallic μ-alkylidene complexes

DOI: 10.1016/0022-328X(90)87188-J

Source and publish data:

Journal of Organometallic Chemistry p. C31 - C35 (1990)

Update date:2022-08-17

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Authors:

Casey, Charles P.

Askham, Frederic R.

Petrovich, Lori M.

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Article abstract of DOI:10.1016/0022-328X(90)87188-J

The reaction of two equivalents of Cp2ZrHCl (1) with Cp(CO)2Re=CHR (2, R = CH2CH2CMe3; 4, R = CH3) led to the formation of the heterobimetallic μ-alkylidene complexes Cp2Zr(μ-CHR)(μ,η¹,η²-CO)Re(CO)Cp (3, R = CH2CH2CMe3; 5, R = CH3).

Full text of DOI:10.1016/0022-328X(90)87188-J

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