Zur Lewisaciditat von Nickel(0) VII. Alkalimetall-μ3-hydrido-tetrakis(ethen)diniccolat(0)-Komplexe: (pmdta)Li(μ3-H)Ni2(C2H4)4 und (pmdta)Na(μ3-H)Ni2(C2H4)4

DOI: 10.1016/0022-328X(88)80455-8

Source and publish data:

Journal of Organometallic Chemistry p. 257 - 262 (1988)

Update date:2022-08-11

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Authors:

Porschke, Klaus Richard

Wilke, Gunther

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Article abstract of DOI:10.1016/0022-328X(88)80455-8

Ni(C2H4)3 reacts with alkalimetal hydridoaluminates or -gallates M_AHA1/GaR3 and M_AH2AlR2 (R = alkyl) in ether/pmdta at temperatures between -70 and -20 ^oC to yield the ion pair complexes (pmdta)M_A(μ₃-

Full text of DOI:10.1016/0022-328X(88)80455-8

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