Tetrahedron p. 2569 - 2574 (1988)
Update date:2022-08-16
Topics:
Jain, Ajay K.
Velu, V. K.
Sarma, K. N.
Rate constants for the aminolysis of a few O-aryl oximes with several primary alkyl amines, CH3NH2-------C6H12NH2 in 1:1 water-acetonitrile are reported.Reactions of methylamine with substrates possessing poor nucleofugues are very weakly sensitive to base catalysis while reactions of higher amines are not.Slightly higher rate of long chain amine may be considered as a consequence of hydrophobic interaction.Cationic micelles of cetyltrimethyl ammonium bromide enhance the rate.Magnitude of micellar catalysis increases towards higher amines.
View More
Rudong Zhenfeng Yiyang Chemical Co., Ltd.
Contact:0513-84573047
Address:South Fengli Town, Rudong County, Jiangsu Province, China
Shanghai Forever Synthesis Co.,Ltd.
Contact:021-61124658
Address:Zhoukang Road,Pudong New District,Shanghai,China
Contact:0086-29-88315623
Address:S711, Innovation Bldg No.25 Gaoxin 1st Rd, Xian P.R of China 710075
Contact:+86-18653358619
Address:zibo
Contact:13357117572
Address:No.149 Shiji dadao Road.
Doi:10.1021/jo01074a631
(1960)Doi:10.1016/j.bmc.2014.09.028
(2014)Doi:10.1021/ja01213a053
(1946)Doi:10.1248/bpb.21.641
(1998)Doi:10.1039/b506046j
(2005)Doi:10.3390/molecules191118953
(2014)
