Silylformylation catalyzed by Rh and Rh-Co mixed metal complexes and its application to the synthesis of pyrrolizidine alkaloids

DOI: 10.1016/S0040-4020(01)87260-4

Source and publish data:

Tetrahedron p. 5431 - 5444 (1993)

Update date:2022-08-28

Topics:

Authors:

Ojima Ojima

Donovan Donovan

Eguchi Eguchi

Shay Shay

Ingallina

Korda Korda

Zeng Zeng

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Article abstract of DOI:10.1016/S0040-4020(01)87260-4

Reactions of hydrosilanes with 1-hexyne catalyzed by Co₂Rh₂(CO)₁₂, Rh₄(CO)₁₂, (BuNC)₄RhCo(CO)₄, and Rh(acac)(CO)₂ at 25°C and atmospheric pressure to 10 atm of carbon

Full text of DOI:10.1016/S0040-4020(01)87260-4

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Product name:Hexanal, 2-[(dimethylphenylsilyl)methylene]-, (2Z)-

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