Electronic and Ion-Pairing Effects of a Methyl Group on a Diphenylmethyl Anion Determined by Restricted Aryl Rotation

DOI: 10.1021/jo00200a014

Source and publish data:

Journal of Organic Chemistry p. 5091 - 5093 (1984)

Update date:2022-08-16

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Authors:

Bank, Shelton

Marcantonio, Richard P.

Bushweller, C. H.

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Article abstract of DOI:10.1021/jo00200a014

The compound <(2,4,6-trideuteriophenyl)(4-methylphenyl)methyl>lithium has been prepared and studied by 1H DNMR.A complete line shape analysis of the spectrum allows unambiguous phenyl ring assignment to the differential aryl barriers to rotation.Solvent v

Full text of DOI:10.1021/jo00200a014

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