Vinylic Organoboranes. 13. A Convenient Stereospecific Synthesis of (Z)-1-Halo-1-alkenes from 1-Alkynes via (E)-1-Alkenylborane Derivatives with Halogens

DOI: 10.1021/jo00287a018

Source and publish data:

Journal of Organic Chemistry p. 6068 - 6075 (1989)

Update date:2022-08-11

Topics:

Authors:

Brown, Herbert C.

Subrahmanyam, Chitti

Hamaoka, Tsutomu

Ravindran, Nair

Bowman, Donald H.

et al. et al.

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Article abstract of DOI:10.1021/jo00287a018

The reaction of (E)-1-alkenylborane derivatives with bromine under various conditions was investigated, and a simple stereospecific synthesis of (Z)-1-bromo-1-alkenes has been developed.Addition of bromine to (E)-1-alkenyldisiamylborane, derived from the

Full text of DOI:10.1021/jo00287a018

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