Bulletin of the Chemical Society of Japan p. 3547 - 3551 (1985)
Update date:2022-08-28
Topics:
Kajigaeshi, Shoji
Mori, Seiji
Fujisaki, Shizuo
Kanemasa, Shuji
Pyrido<2,1-a>isoindole cycloadds to olefinic dipolarophiles in a highly exo-selective fashion giving the kinetically controlled cycloadducts which gradually isomerize into the Michael adducts.With acetylenic dipolarophiles, the hydrogen-migrated cycloadducts are the only products.The mechanism of cycloadditions is discussed.
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(1973)
