2 + 2 + 2 cycloaddition vs radical ion chemistry in the photoreactions of 1,2,4,5-benzenetetracarbonitrile with alkenes in acetonitrile

DOI: 10.1021/ja00101a027

Source and publish data:

Journal of the American Chemical Society p. 10070 - 10075 (1994)

Update date:2022-08-17

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Authors:

Vanossi, Matteo

Mella, Mariella

Albini, Angelo

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Article abstract of DOI:10.1021/ja00101a027

Irradiation of 1,2,4,5-benzenetetracarbonitrile (TCB) in acetonitrile in the presence of 1-hexene leads to two isomeric tetrahydroisoquinolines through a 2 + 2 + 2 cycloaddition between TCB, the alkene, and MeCN. The process occurs with moderate quantum y

Full text of DOI:10.1021/ja00101a027

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