A convenient synthesis of protected and free homoallylic alcohols: Catalytic use of dibutyltin dichloride in the allylation of aldehydes with allyltributyltin

DOI: 10.1016/0040-4039(96)00719-8

Source and publish data:

Tetrahedron Letters p. 3955 - 3958 (1996)

Update date:2022-08-16

Topics:

Authors:

Whitesell, James K.

Apodaca, Richard

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Article abstract of DOI:10.1016/0040-4039(96)00719-8

A new procedure for the allylation of aldehydes with allyltributyltin in the presence of 10 mol% dibutyltin dichloride and either an acid chloride or trimethylsilyl chloride has been developed. Homoallylic esters, carbonates, trimethylsilyl ethers, and alcohols were obtained in up to 99% yield.

Full text of DOI:10.1016/0040-4039(96)00719-8

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