Observation of the gas-phase infrared spectrum of BH3

Article abstract of DOI:10.1063/1.453135

The gas-phase spectrum of BH3 was detected for the first time by diode laser spectroscopy through the observation of the ν₂ band.The borane was produced by photolysis of B2H6 or BH3CO with an ArF excimer la,ser.The same spectrum was obtained by a discharge in a B2H6 and He mixture.Line assignments were made for the Q-branch series with J = K of the ν₂ band; effects due to Coriolis perturbations by the ν₄ state were recognized.

Full text of DOI:10.1063/1.453135

Observation of the gasphase infrared spectrum of BH3
Kentarou Kawaguchi, J. E. Butler, Chikashi Yamada, S. H. Bauer, Tatsuya Minowa, Hideto Kanamori, and
Eizi Hirota
Citation: The Journal of Chemical Physics 87, 2438 (1987); doi: 10.1063/1.453135
View online: http://dx.doi.org/10.1063/1.453135
View Table of Contents: http://scitation.aip.org/content/aip/journal/jcp/87/5?ver=pdfcov
Published by the AIP Publishing
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
30.88.90.110 On: Fri, 19 Dec 2014 07:13:36
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
30.88.90.110 On: Fri, 19 Dec 2014 07:13:36
1

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
30.88.90.110 On: Fri, 19 Dec 2014 07:13:36
1

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
30.88.90.110 On: Fri, 19 Dec 2014 07:13:36
1