New Photochemically Labile Protecting Group for Phosphates

DOI: 10.1246/cl.1993.1179

Source and publish data:

Chemistry Letters p. 1179 - 1182 (1993)

Update date:2022-08-17

Topics:

Authors:

Furuta, Toshiaki

Torigai, Hiromi

Osawa, Tomoko

Iwamura, Michiko

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Article abstract of DOI:10.1246/cl.1993.1179

New photochemically labile phosphate protecting group was developed.These phosphate esters have high molar extinction coefficient (ε₃₄₀=34500 dm³ mol^-1cm^-1) and rapidly release parent phosphates upon irradiation (>300 nm) with high quantum efficiency for disappearance (φ_dis=0.22 at 340 nm).

Full text of DOI:10.1246/cl.1993.1179

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