Unexpected Single Electron Transfer Catalysed Cyclisation of Prenyl Sulphone Dimer. Evidence for Radical Anion Coupling in the Outer-sphere Oxidation of Prenyl Sulphone Carbanion

DOI: 10.1039/c39890001543

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Journal of the Chemical Society. Chemical communications p. 1543 - 1545 (1989)

Update date:2022-08-05

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Authors:

Amatore, Christian

Thiebault, Andre

Verpeaux, Jean-Noel

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Article abstract of DOI:10.1039/c39890001543

Preparative electrochemical oxidation of metallated phenyl prenyl sulphone leads to a previously unknown cyclic dimer, the formation of which has been rationalized, providing strong evidence for a radical-anion coupling mechanism in outer-sphere oxidative

Full text of DOI:10.1039/c39890001543

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