Optically active phenanthrolines in asymmetric catalysis. IV. Enantioselective hydrosilylation of acetophenone by rhodium/chiral alkyl phenanthroline catalysts

DOI: 10.1016/S0957-4166(00)82284-3

Source and publish data:

Tetrahedron Asymmetry p. 937 - 942 (1990)

Update date:2022-08-03

Topics:

Authors:

Gladiali

Pinna Pinna

Delogu Delogu

Graf Graf

Brunner Brunner

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Article abstract of DOI:10.1016/S0957-4166(00)82284-3

The in situ catalysts prepared from [Rh(Cod)Cl]₂ (Cod = 1,5-cyclooctadiene) and chiral alkylphenanthroline ligands 1-6 display a remarkable activity in the asymmetric hydrosilylation of acetophenone affording, after hydrolysis, the expected 1-p

Full text of DOI:10.1016/S0957-4166(00)82284-3

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