Catalytic asymmetric hydrogenation of imines with a chiral titanocene catalyst: Kinetic and mechanistic investigations

DOI: 10.1021/ja00105a011

Source and publish data:

Journal of the American Chemical Society p. 11703 - 11714 (1994)

Update date:2022-08-10

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Authors:

Willoughby, Christopher A.

Buchwald, Stephen L.

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Article abstract of DOI:10.1021/ja00105a011

A kinetic study of the asymmetric titanocene-catalyzed imine hydrogenation has revealed the rate law to be rate = k_obs[Ti][H₂], for cyclic imine 2 and acyclic imine 4. This rate law is consistent with a mechanism in which the imine r

Full text of DOI:10.1021/ja00105a011

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