New tandem Zn-promoted brook rearrangement/ene-allene carbocyclization reactions

DOI: 10.1021/ol052237b

Source and publish data:

Organic Letters p. 5313 - 5316 (2005)

Update date:2022-08-16

Topics:

Authors:

Unger, Rozalia

Cohen, Theodore

Marek, Ilan

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Article abstract of DOI:10.1021/ol052237b

(Chemical Equation Presented) A new tandem reaction was developed for the carbocyclization reaction of propargylic zinc reagents. First, we have shown that zinc salt promotes the Brook rearrangement into the carbanionic species followed by a stereospecifi

Full text of DOI:10.1021/ol052237b

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