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Synthesis of the Ethyl Oxalyl Tetracarbonyl Iron Anion -, its Methylation at the Metal into (CO)4Fe(Me)(COCO2Et) and Further Carbon-Carbon Coupling into Ethyl Pyruvate

DOI: 10.1039/c39890001671

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1671 - 1673 (1989)

Update date:2022-08-11

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Authors:

Sabo-Etienne, SylvianeSabo-Etienne, Sylviane

Larsonneur, Anne-MarieLarsonneur, Anne-Marie

Abbayes, Herve desAbbayes, Herve des

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Article abstract of DOI:10.1039/c39890001671

The stable anion <(CO)FeCOCO2Et>- (2) is methylated at the metal by reaction with MeSO3CF3 at -50 deg C to give (CO)4Fe(Me)(COCO2Et) (3) characterized in situ by 1H and 13C NMR; at -30 deg C

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